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Abstract: OH-Al solutions were prepared by adding appropriate amounts of NaOH to AlCl3 to obtain OH/Al mole ratios of 2.0, 2.5, 2.7, 3.0, and 3.3 in the final suspension. Solid Na2SO4 and Georgia kaol...
Hydroxy-Al-montmorillonite was prepared by mixing Na-Wyoming montmorillonite with Al(OH)2.5 polycations and aging the mixture for 10 days. The reactions of this complex with citric acid at millimolar ...
Three montmorillonite samples, from Wyoming (particle size <0.2 &micro;m, 4.6 wt. % Fe2O3), Greece (<14 &micro;m, 6.5 wt. % Fe2O3), and Poland (0.5 wt. % Fe2O3, two fractions <2 &micro;m and 2–10 &mic...
The treatment of smectites with a hydroxy-Al polymer produced chemically modified clays that had much greater affinities for chlorinated dioxins and biphenyls than untreated clays. For hydroxy-Al-trea...
The sintering of montmorillonites pillared by hydroxy-Al species was investigated by several techniques. The change of the microporosity of the pillared interlayer clay with temperature shows that sin...
Beidellite was synthesized hydrothermally from a noncrystalline gel at 320°C and 130 bar pressure. The beidellitic character of the product was verified by infrared spectroscopy on the NH4+-exchanged ...
Copper adsorption on a hydroxy-aluminum-hectorite complex (OH-Al-hectorite) at pH 4.5, 5.7, 7.4, and 7.8 was examined by means of electron spin resonance. The spectra of these samples were compared to...
Interaction of La3+ and Ce3+-exchanged hectorites with oligomeric hydroxy-Al cations results in the formation of cross-linked hectorites possessing moderately high surface areas (∼220–280 m2/g) ...
Cross-linking of Li-montmorillonite by hydroxy-aluminum oligomers was performed in a specially constructed mixing apparatus. Observations on flocculation and solution composition were carried out duri...
A stable porous system consisting of montmorillonite cross-linked by Al-hydroxide oligomers was synthesized by reacting at room temperature an aqueous solution of such oligomers with a unit-layer disp...
Abstract: The hypothesis tested was that macroscopic swelling of montmorillonitic clays is reduced by the presence of interlayer minerals. Fine and coarse clay fractions of Camargo and Panther Greek b...
A specimen montmorillonite (Arizona bentonite) was treated with hydroxy-aluminum solutions of various basicity. The cation exchange sites of this clay were found not to be homogeneous in their strengt...

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