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Electron Compensation Effect Suppressed Silver Ion Release and Contributed Safety of Au@Ag Core-Shell Nanoparticles
Au@Ag core-shell electron compensation safety biomedical application
2023/6/21
Silver nanoparticles (Ag NPs) have promising plasmonic properties, however, they are rarely used in biomedical applications because of their potent toxicity. Herein, an electron compensation effect fr...
New Paper Published in Nature Communications titled, “Exact exchange-correlation potentials from ground-state electron densities”
Published titled Exact potentials electron densities
2019/10/10
The quest for accurate exchange-correlation functionals has long remained a grand challenge in density functional theory (DFT), as it describes the many-electron quantum mechanical behavior through a ...
Photochemistry of a Bacterial Photosynthetic Reaction Center Missing the Initial Bacteriochlorophyll Electron Acceptor
Carbon nanotubes Composite Terahertz properties
2016/5/25
A novel chromophore composition of the bacterial photosynthetic reaction center (RC) has been discovered: RCs lacking the L-side monomeric bacteriochlorophyll chromophore result from mutation of the n...
Temperature Dependence of Electron Transfer to the M-Side Bacteriopheophytin in Rhodobacter capsulatus Reaction Centers
hydrogenation fatty acids stereoselectivity kinetics
2016/5/25
Subpicosecond time-resolved absorption measurements at 77 K on two reaction center (RC) mutants of Rhodobacter capsulatus are reported. In the D(LL) mutant the D helix of the M subunit has been substi...
Probing Excited-State Electron Transfer by Resonance Stark Spectroscopy:4.Mutations near BL in Photosynthetic Reaction Centers Perturb Multiple Factors that Affect BL/fBL+HL
Excited-State Electron Transfer Resonance Stark Spectroscopy Mutations near BL Photosynthetic Reaction Centers Perturb Multiple Factors BL/fBL+HL
2016/5/24
Stark spectra have been obtained in the region of absorption by the accessory bacteriochlorophylls (the B-band region around 800 nm) in Rhodobacter sphaeroides reaction centers. The Stark spectra in t...
Probing Excited-State Electron Transfer by Resonance Stark Spectroscopy:3.Theoretical Foundations and Practical Applications
contracted basis Lanczos algorithm methane vibrational spectroscopy
2016/5/24
Resonance Stark effects are nonclassical Stark effects associated with excited-state charge-transfer processes. The theory of resonance Stark effects developed in Part 2 of this series is generalized ...
Probing Excited State Electron Transfer by Resonance Stark Spectroscopy.II.Theory and Application
Excited State Electron Resonance Stark Spectroscopy Theory Application
2016/5/23
A theory of the resonance Stark effect data reported in part 1 (preceding paper in this issue) is developed. The model used involves a weak charge resonance interaction between the excited state of an...
Probing Excited State Electron Transfer by Resonance Stark Spectroscopy.I.Experimental Results for Photosynthetic Reaction Centers
adatoms bismuth photoelectron diffraction silicon
2016/5/23
Higher order Stark spectroscopy has recently been introduced and applied to characterize the electrooptic properties of chromophores in bacterial photosynthetic reaction centers.1 In the course of the...
Effects of Applied Electric Fields on the Quantum Yields for the Initial Electron Transfer Steps in Bacterial Photosynthesis:II.Dynamic Stark Effect
Applied Electric Fields Quantum Yields Initial Electron Transfer Steps Bacterial Photosynthesis Dynamic Stark Effect
2016/5/23
The quantum yield of the initial charge separation steps in bacterial photosynthetic reaction centers has been shown to be reduced in an applied electric field [Part I, Lao et al., J. Phys. Chem. 97 (...
Temperature Dependence of the Electric Field Modulation of Electron-Transfer Rates:Charge Recombination in Photosynthetic Reaction Centers
solar energy inorganic, organic, physical and analytical chemistry photosynthesis reaction kinetics electric fields electron transfer entropy experimental data free energy mathematical models
2016/5/23
The rates of electron-transfer reactions can be systematically varied by application of external electric fields. The electric field effect on the charge recombination rate constant of the state P[sup...
Distance Dependence of Electron-Transfer Reactions in Organized Systems:The Role of Superexchange and Non-Condon Effects in Photosynthetic Reaction Centers
Distance Dependence Electron-Transfer Reactions Organized Systems Superexchange Non-Condon Photosynthetic Reaction Centers
2016/5/23
Extremely long distance electron transfer is observed in some photosynthetic reaction centers. For several charge recombination reactions, the rate appears to fall off much more slowly with distance t...
Electric Field Effects on Emission Line Shapes when Electron Transfer Competes with Emission:an Example from Photosynthetic Reaction Centers
RHODOBACTER-SPHAEROIDES R-26 PRIMARY CHARGE SEPARATION RHODOPSEUDOMONAS-VIRIDIS BACTERIAL PHOTOSYNTHESIS FEMTOSECOND SPECTROSCOPY PROTEIN SUBUNITS 3A RESOLUTION PRIMARY DONOR SPECTRA
2016/5/23
Electron-transfer reactions are expected to be particularly sensitive to externally applied electric fields because of the presence of charge-separated, dipolar states, and the effects of the field on...
Electric Field Effects on the Initial Electron-Transfer Kinetics in Bacterial Photosynthetic Reaction Centers
solar energy inorganic, organic, physical and analytical chemistry photosynthetic reaction centers electron transfer calculation methods electric fields kinetics low temperature photochemistry chemistry 140500* -- solar energy conversion
2016/5/23
The effect of an applied electric field on the kinetics of the initial picosecond electron-transfer reaction in Rb. sphaeroides reaction centers has been measured in isotropic samples at 77 K. The net...
Electric Field Modulation of Electron Transfer Reaction Rates in Isotropic Systems:Long-Distance Charge Recombination in Photosynthetic Reaction Centers
CORROSION PRODUCT NICKEL FERRITE MAGNETITE PH SOLUBILITY PWR STEAM GENERATORS
2016/5/23
A general method is demonstrated for experimentally obtaining the rate constant of electron transfer as a function of the free energy of the reaction in nonoriented systems. An external electric field...
Structure-Based Analysis of the Initial Electron Transfer Step in Bacterial Photosynthesis: Electric Field Induced Fluorescence Anisotropy
Fluorescence Electric fields Electron transfer Transfer reactions Anisotropy
2016/5/20
The fluorescence intensity from randomly oriented, immobilized Rb. sphaeroides reaction centers at 77 K increases in the presence of an externally applied electric field. We have proposed that this in...